MEPC.130(53) Guidelines for On-Board Exhaust Gas-SOx Cleaning Systems

Guidelines revoked by resolution MEPC.170(57)

Resolution MEPC.130(53)

GUIDELINES FOR ON-BOARD EXHAUST GAS-SOX CLEANING SYSTEMS

(Adopted on 22 July 2005)

 

 

THE MARINE ENVIRONMENT PROTECTION COMMITTEE,

 

RECALLING Article 38(a) of the Convention on the International Maritime Organization concerning the functions of the Marine Environment Protection Committee (the Committee) conferred upon it by international conventions for the prevention and control of marine pollution,

 

RECALLING ALSO that the Conference of Parties to the International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78), held in September 1997, adopted the Protocol of 1997 to amend MARPOL 73/78 with a new Annex VI on the Prevention of Air Pollution from Ships,

 

NOTING that the 1997 Conference by regulation 14(4)(b) of Annex VI, agreed that ships within a SOx emission control area are permitted to operate with an exhaust gas cleaning system approved by the Administration and taking into account guidelines to be developed by the Organization,

 

BEING AWARE that the Protocol of 1997 entered into force on 19 May 2005 and that exemptions from the requirements for SOx emission control areas will cease on 18 May 2006,

 

HAVING CONSIDERED the recommendation made by the Sub-Committee on Ship Design and Equipment at its forty-eighth session,

 

1. ADOPTS the Guidelines for exhaust gas-SOx cleaning systems, as set out in the Annex to this resolution;

 

2. INVITES Governments to apply the Guidelines from the date of their adoption.

 

Annex.

GUIDELINES FOR EXHAUST GAS-SOx CLEANING SYSTEMS -MARPOL ANNEX VI, REGULATION 14(4)(b)

 

INTRODUCTION

 

Regulation 14(4) of Annex VI to MARPOL 73/78 requires ships within SOx emission control areas to either use fuel oil with a sulphur content not exceeding 1.5% or apply an exhaust gas (SOx) cleaning system (EGCS-SOx) to reduce the total emission of SOx to 6.0g/kWh. (6.0 g SOx/kWh or less should be calculated as the total weight of sulphur dioxide emission). The EGCS-SOx unit is to be approved by the Administration taking into account guidelines developed by the Organization.

 

Similar to a NOx emission reduction system, a EGCS-SOx unit may be type approved subject to periodic parameter and emission checks or the system may be equipped with a continuous emission monitoring system. These guidelines have been developed with the intention of being objective and performance oriented. Introduction of the SO2 (ppm) / CO2 (%) ratio method would simplify the monitoring of SOx emission and facilitate type approval of the EGCS-SOx unit. See Appendix I for the rationale explaining the use of SO2 (ppm) / CO2 (%) as the basis for system monitoring.

 

These Guidelines are recommendatory in nature, however, Administrations are invited to base their implementation on these guidelines.

 

SAFETY NOTE

 

Due attention is to be given to the safety implications related to the handling and proximity of exhaust gases, the measurement equipment and the storage and use of cylindered pure and calibration gases. Sampling positions and access staging should be such that this monitoring may be performed safely. In locating discharge outlet of waste water used in the EGCS-SOx unit, due consideration should be given to the location of the ship's sea water inlet and other implications of the acidic nature of such water.

 

SCHEME A.
EGCS-SOx UNIT TYPE APPROVAL AND CERTIFICATION

 

Unit certification of Exhaust Gas-SOx Cleaning Systems (EGCS-SOx) by the Administration with subsequent in service verification at survey intervals by indirect means together with unit use monitoring.

 

1. GENERAL

 

1.1 Purpose

 

The purpose of these Guidelines is to specify the requirements for the design, testing, survey and certification of exhaust gas cleaning-SOx systems (EGCS-SOx) to ensure that they comply with the requirements of regulation 14(4)(b) of Annex VI of MARPOL 73/78.

 

1.2 Application

 

1.2.1 These Guidelines apply to any EGCS-SOx unit as fitted to fuel oil combustion machinery, excluding shipboard incinerators, installed onboard a ship which is to operate within a SOx Emission Control Area (SECA).

 

1.2.2 These Guidelines cover only the certification, survey, and testing of the EGCS-SOx unit for compliance with regulation 14(4)(b) of Annex VI.

 

1.3 Definitions

 

"ppm" means "parts per million". It is assumed that ppm is measured by gas analysers on a molar basis, assuming ideal micro-moles of substance per mole of total amount (µmol/mol), but ppm is used in order to be consistent with units in the NOx Technical Code.

 

"Fuel oil combustion unit" means any engine, boiler, gas turbine, or other fuel oil fired equipment.

 

2. SURVEY AND CERTIFICATION

 

2.1 General

 

2.1.1 Prior to use within a SECA, each EGCS-SOx unit should be issued with a SECA Compliance Certificate (SCC) by the Administration.

 

2.1.2 The EGCS-SOx unit should be subject to survey on installation and at Initial, Annual/Intermediate and Renewals Surveys by the Administration, irrespective of whether or not the ship is in a SECA at the time of Survey.

 

2.1.3 The ship's SCC should be duly endorsed at each survey as required by 2.1.2.

 

2.1.4 In accordance with regulation 10, EGCS-SOx units may also be subject to inspection by PSC when operating within a SECA.

 

2.2 Procedures for the certification of an EGCS-SOx unit

 

2.2.1 In order to meet the requirements of 2.1.1 either prior to, or after installation onboard, each EGCS-SOx unit should be certified as meeting the emission limit of 6.0 g SOx/kWh under the operating conditions and restrictions as given by the EGCS-SOx Technical Manual (ETM) as approved by the Administration.

 

2.2.2 Determination of the emission value should be in accordance with the provisions of these Guidelines.

 

2.2.3 Each EGCS-SOx unit meeting the requirements of 2.2.1 should be issued by the Administration with a SCC.

 

2.2.4 Application for a SCC should be made by the EGCS-SOx manufacturer, shipowner or other party.

 

2.2.5 Subsequent EGCS-SOx units of the same design and rating as that certified under 2.2.1 may be issued with SCC by the Administration without the need for testing in accordance with 2.2.1 subject to section 4.2 of these Guidelines.

 

2.2.6 EGCS-SOx units of the same design, but with ratings different from that certified under 2.2.1 may be accepted by the Administration subject to section 4.3 of these Guidelines.

 

2.2.7 EGCS-SOx units which treat only part of the exhaust gas flow of the uptake in which they are fitted should be subject to special consideration by the Administration to ensure that under all defined operating conditions that the overall emission value of the exhaust gas down stream of the system is no more than 6.0 g SOx /kWh.

 

2.3 EGCS-SOx Technical Manual

 

2.3.1 Each EGCS-SOx unit is to be supplied with a EGCS-SOx Technical Manual (ETM) provided by the Manufacturer. This ETM should, as a minimum, contain the following information:

 

(a) the identification of the unit (manufacturer, model/type, serial number and other details as necessary) including a description of the unit and any required ancillary systems;

 

(b) the operating limits, or range of operating values, for which the unit is certified. These should, as a minimum, include:

 

(i) maximum and, if applicable, minimum mass flow rate of exhaust gas;

 

(ii) the power, type and other relevant parameters of the fuel oil combustion unit for which the EGCS-SOx unit is to be fitted. In the cases of boilers, the maximum air/fuel ratio at 100% load should also be given. In the cases of diesel engines whether the engine is of 2 or 4 stroke cycle;

 

(iii) maximum and minimum wash water flow rate, inlet pressures and minimum inlet water alkalinity (pH);

 

(iv) exhaust gas inlet temperature ranges and maximum exhaust gas outlet temperature with the EGCS-SOx unit in operation;

 

(v) exhaust gas differential pressure range and the maximum exhaust gas inlet pressure with the fuel oil combustion unit operating at MCR or 80% of power rating whichever is appropriate;

 

(vi) salinity levels or fresh water elements necessary to provide adequate neutralizing agents; and

 

(vii) other factors concerning the design and operation of the EGCS-SOx unit relevant to achieving a maximum emission value no higher than 6.0 g SOx/kWh;

 

(c) any requirements or restrictions applicable to the EGCS-SOx unit or associated equipment necessary to enable the unit to achieve a maximum emission value no higher than 6.0 g SOx/kWh;

 

(d) maintenance, service or adjustment requirements in order that the EGCS-SOx unit can continue to achieve a maximum emission value no higher than 6.0 g SOx/kWh;

 

(e) the means by which the EGCS-SOx unit is to be surveyed to ensure that its performance is maintained and that the unit is used as required (see section 6);

 

(f) through range performance variation in wash water characteristics;

 

(g) design requirements of the wash water system; and

 

(h) the SCC.

 

2.3.2 The ETM should be approved by the Administration.

 

2.3.3 The ETM should be retained onboard the ship onto which the EGCS-SOx unit is fitted. The ETM should be available for surveys as required.

 

2.3.4 Additions, deletions or amendments to the ETM should be approved by the Administration. Where additions, deletions or amendments to the ETM are separate to the ETM as initially approved, they should be retained with the ETM and should be considered as part of the ETM.

 

2.3.5 As an alternative to the maximum emission rate stipulated in 2.3.1(b)(vii) of 6.0 g SOx/kWh, SO2 (ppm) / CO2 (% ) ratio of 65 or below, measured downstream of EGCS-SOx unit may be used.

 

3. EMISSION LIMIT

 

3.1 Each EGCS-SOx unit should be capable of reducing emissions to no more than 6.0 g SOx/kWh at any load point when operated in accordance with the criteria as given within 2.3.1(b), as specified in paragraphs 3.2 through 3.5 of these Guidelines, and as excepted in paragraphs 3.7 and 3.8.

 

3.2 EGCS-SOx units fitted to main propulsion diesel engines should meet the requirements of 3.1 at all loads between 25-100% of the load range of the engines to which they are fitted.

 

3.3 EGCS-SOx units fitted to auxiliary diesel engines should meet the requirements of 3.1 at all loads between 10-100% of the load range of the engines to which they are fitted.

 

3.4 EGCS-SOx units fitted to diesel engines which supply power for both main propulsion and auxiliary purposes should meet the requirements of 3.3.

 

3.5 EGCS-SOx units fitted to boilers should meet the requirements of 3.1 at all loads between 10-100% of the load range (steaming rates) of the boilers to which they are fitted.

 

3.6 In order to demonstrate performance, emission measurements should be undertaken, with the agreement of the Administration, at a minimum of four load points. One load point is to be at 95-100% of the maximum exhaust gas mass flow rate for which the unit is to be certified. One load point is to be within + 5% of the minimum exhaust gas mass flow rate for which the unit is to be certified. The other two load points are to be equally spaced between the maximum and minimum exhaust gas mass flow rates. Where there are discontinuities in the operation of the system the number of load points should be increased, with the agreement of the Administration, so that it is demonstrated that the required performance over the stated exhaust gas mass flow rate range is retained. Additional intermediate load points should be tested if there is evidence of an emission peak below the maximum exhaust gas mass flow rate and above, if applicable, the minimum exhaust gas flow rate. These additional tests should be sufficient number as to establish the emission peak value.

 

3.7 For loads below those specified in 3.2 to 3.5, the EGCS-SOx unit should continue in operation. In those cases where the fuel oil combustion equipment may be required to operate under idling conditions, the SO2 emission concentration (ppm) at standardized O2 concentration (15.0% diesel engines, 3.0% boilers) should not exceed 50 ppm.

 

3.8 Alternatively to the provisions of 3.2-3.5 and 3.7, each EGCS-SOx unit should be capable of reducing emissions to 65 or below, in SO2 (ppm) / CO2 (%) ratio at any load point when operated in accordance with the criteria as given within 2.3.1(b) and 2.3.4.

 

4. APPROVAL OF AN EGCS-SOx UNIT

 

4.1 Unit approval

 

4.1.1 An EGCS-SOx unit should be capable of meeting the limit value of 6.0 g SOx/kWh (other than as given in section 3) with fuel oils of up to 4.5% m/m sulphur and for the range of operating parameters, as listed in 2.3.1(b), for which they are to be approved.

 

4.1.2 Where testing is not to be undertaken with fuel oils of 4.5% m/m sulphur content or above, testing should be undertaken to demonstrate the effect of fuel oil sulphur content on system performance. In such cases a minimum of two tests, in accordance with section 3 as appropriate, should be performed. These need not be sequential and could be undertaken on two different, but identical, EGCS-SOx units. The minimum sulphur content of the fuel oil used in one test should not be less than 2.0% m/m sulphur. The other fuel oil should have a sulphur content of at least 1.0% m/m sulphur above that of the lower sulphur content fuel oil. The EGCS-SOx unit manufacturer should justify, on the basis of the above considerations, and other testing as may be required, that the EGCS-SOx unit would meet the required limit of 6.0 g SOx/kWh when used with a fuel oil of 4.5% m/m sulphur.

 

4.1.3 The maximum and, if applicable, minimum exhaust gas mass flow rate of the unit should be stated. The effect of variation of the other parameters defined in 2.3.1(b) should be justified by the equipment manufacturer. The effect of variations in these factors is to be assessed by testing or otherwise as appropriate. No variation in these factors, or combination of variations in these factors, should be such that the emission value of the EGCS-SOx unit would be in excess of 6.0 g SOx/kWh.

 

4.1.4 Data obtained in accordance with this section should be submitted to the Administration for approval together with the ETM.

 

4.2 Serially manufactured units

 

In the case of nominally similar EGCS-SOx units of the same mass flow ratings as that certified under 4.1, and to avoid the testing in accordance with 2.2.1 each EGCS-SOx unit, the equipment manufacturer may submit, for acceptance by the Administration, a conformity of production arrangement. The certification of each EGCS-SOx unit under this arrangement should be subject to such surveys that the Administration may consider necessary as to assure that each EGCS-SOx unit has an emission value of not more than 6.0 g SOx/kWh when operated in accordance with the parameters defined in 2.3.1(b).

 

4.3 Product range approval

 

4.3.1 In the case of an EGCS-SOx unit of the same design, but of different maximum exhaust gas mass flow capacities, the Administration may accept, in lieu of tests on an EGCS-SOx unit of all capacities in accordance with section 4.1, tests of EGCS-SOx systems of three different capacities provided that the three tests are performed at intervals including the highest, lowest and one intermediate capacity rating within the range.

 

4.3.2 Where there are significant differences in the design of EGCS-SOx units of different capacities, this procedure should not be applied unless it can be shown, to the satisfaction of the Administration, that in practice those differences do not materially alter the performance between the various EGCS-SOx unit types.

 

4.3.3 For EGCS-SOx units of different capacities, the sensitivity to variations in the type of combustion machinery to which they are fitted should be detailed together with sensitivity to the variations in the parameters listed in 2.3.1(b). This should be on the basis of testing, or other data as appropriate.

 

4.3.4 The effect of changes of EGCS-SOx capacity on wash water characteristics should be detailed.

 

4.3.5 All supporting data obtained in accordance with this section, together with the ETM for each capacity unit, should be submitted to the Administration in accordance with 4.1.6.

 

4.3.6 An SO2 (ppm) / CO2 (%) ratio of 65 may be used for emission limit value specified in 4.1.2, 4.1.3 and 4.2.

 

5. EMISSION TESTING

 

5.1 Emission testing should follow the requirements of the NOx Technical Code, chapter 5, and associated Appendices, except as provided for in these Guidelines.

 

5.2 CO2, O2 and SO2 should be measured. CO2 and O2 as % to a precision of +/-1% of the true reading for a signal averaging time of 10 seconds, but not less than a lower detectable limit of 5 ppm.

 

5.3 SO2 should be measured on a dry or wet basis using analysers operating on NDIR or NDUV principles and with additional equipment such as dryers as necessary. Other systems or analysers may be accepted, subject to the approval of the Administration, provided they yield equivalent results to those of the equipment referenced above.

 

5.4 An exhaust gas sample for SO2 should be obtained from a representative sampling point downstream of the EGCS-SOx unit.

 

5.5 SO2 should be monitored on-line using either cross-duct or extractive sample systems.

 

5.6 Extractive exhaust gas samples for SO2 determination should be maintained at a sufficient temperature to avoid condensed water in the sampling system and hence loss of SO2.

 

5.7 If an extractive exhaust gas sample for determination needs to be dried prior to analysis it should be done in a manner which does not result in loss of SO2 in the sample as analysed.

 

5.8 Where SO2 is measured by a cross-duct system, the water content in the exhaust gas stream at that point is also to be determined in order to correct the reading to a dry basis value.

 

5.9 Where the exhaust gas mass flow is to be calculated in accordance with the NOx Technical Code, Appendix 6, the complete combustion case calculations may be used. The exhaust gas mass flow (GEXHW) should be determined in respect of the mass flow into the EGCS-SOx unit.

 

5.10 In applying the NOx Technical Code, equation 15, the dry basis SO2 concentration should be converted to a wet basis value using the dry/wet correction factor applicable to the exhaust gas at entry into the EGCS-SOx unit (NOx Technical Code, equation 11, CO = 0):

 

w = 0.002855, u = w/exhaust gas density in g/m3 at 0°C and 101.3 kPa

 

5.11 The fuel oil as used in the test should be a residual blend product. A representative sample of that fuel should be analysed in order to establish its chemical composition (carbon, hydrogen and sulphur) together with the other parameters as necessary to establish its grade in accordance with the ISO 8217 specification.

 

5.12 For diesel engines the power should be the uncorrected brake power.

 

5.13 For boilers the "power" should be determined based on the fuel rate and assumed brake specific fuel consumption of 200 g/kWh.

 

5.14 The determined emission value at each test point should be equal to, or less than, 6.0 g SOx/kWh.

 

5.15 In lieu of the testing procedure laid down in 5.9 to 5.10 and 5.12 to 5.14, compliance may be demonstrated by continuous monitoring of and CO2 concentration in the exhaust gas down stream of the EGCS-SOx unit and demonstrating that the SO2 (ppm) / CO2 (%) ratio, at each test point is 65 or below.

 

5.16 Should the SO2 (ppm) / CO2 (%) ratio method be used:

 

(a) The conditions stipulated in 5.4 and 5.5 should also apply to the measurement of CO2 (%) and it is recommended that SO2 and CO2 samples should be obtained at the same location.

 

(b) Measurement of SO2 and CO2 should either be carried out above the respective dew points or on a fully dry basis recognizing that the conditions stipulated in 5.6-5.8 should also apply to the measurement of CO2 (%).

 

(c) The carbon and hydrogen content of the test fuel as stipulated in 5.11 need not be determined.

 

(d) Calculation of the SO2/CO2 ratio should comply with the requirements of Scheme B, section 10.

 

6. PROCEDURES FOR DEMONSTRATING COMPLIANCE WITH EMISSION LIMIT ON BOARD

 


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